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Propagation dynamics of the cosh-Airy vortex(CAiV) beams in a chiral medium is investigated analytically with Huygens–Fresnel diffraction integral formula. The results show that the CAiV beams are split into the left circularly polarized vortex(LCPV) beams and the right circularly polarized vortex(RCPV) beams with different propagation trajectories in the chiral medium. We mainly investigate the effect of the cosh parameter on the propagation process of the CAiV beams.The propagation characteristics, including intensity distribution, propagation trajectory, peak intensity, main lobe's intensity, Poynting vector, and angular momentum are discussed in detail. We find that the cosh parameter affects the intensity distribution of the CAiV beams but not its propagation trajectory. As the cosh parameter increases, the distribution areas of the LCPV and RCPV beams become wider, and the side lobe's intensity and peak intensity become larger. Besides, the main lobe's intensity of the LCPV and RCPV beams increase with the increase of the cosh parameter at a farther propagation distance, which is confirmed by the variation trend of the Poynting vector. It is significant that we can vary the cosh parameter to control the intensity distribution, main lobe's intensity, and peak intensity of the CAiV beams without changing the propagation trajectory. Our results may provide some support for applications of the CAiV beams in optical micromanipulation. 相似文献
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Size controlled synthesis of ornithine‐based polypeptides by ring‐opening polymerization of α‐(amino acid)‐N‐carboxyanhydrides 下载免费PDF全文
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Tailorable PC71BM Isomers: Using the Most Prevalent Electron Acceptor to Obtain High‐Performance Polymer Solar Cells
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Xin‐Xing Zhan Xin Zhang Si‐Min Dai Shu‐Hui Li Xu‐Zhai Lu Dr. Lin‐Long Deng Prof. Su‐Yuan Xie Prof. Rong‐Bin Huang Prof. Lan‐Sun Zheng 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(52):18709-18713
Despite being widely used as electron acceptor in polymer solar cells, commercially available PC71BM (phenyl‐C71‐butyric acid methyl ester) usually has a “random” composition of mixed regioisomers or stereoisomers. Here PC71BM has been isolated into three typical isomers, α‐, β1‐ and β2‐PC71BM, to establish the isomer‐dependent photovoltaic performance on changing the ternary composition of α‐, β1‐ and β2‐PC71BM. Mixing the isomers in a ratio of α/β1/β2=8:1:1 resulted in the best power conversion efficiency (PCE) of 7.67 % for the polymer solar cells with PTB7:PC71BM as photoactive layer (PTB7=poly[[4,8‐bis[(2‐ethylhexyl)oxy]benzo[1,2‐b:4,5‐b′]dithiophene‐2,6‐diyl][3‐fluoro‐2‐[(2‐ethylhexyl)carbonyl]thieno[3,4‐b]thiophenediyl]]). The three typical PC71BM isomers, even though sharing similar LUMO energy levels and light absorption, render starkly different photovoltaic performances with average‐performing PCE of 1.28–7.44 % due to diverse self‐aggregation of individual or mixed PC71BM isomers in the otherwise same polymer solar cells. 相似文献
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Back Cover: Ultrasound‐Driven Secondary Self‐Assembly of Amphiphilic β‐Cyclodextrin Dimers (Chem. Eur. J. 13/2015) 下载免费PDF全文
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Jing Qu Xinran Luo Zhonggang Wang 《Journal of polymer science. Part A, Polymer chemistry》2016,54(13):1969-1977
Tetrakis(4‐(1‐bromoethyl)phenyl)silane is synthesized and utilized to initiate the atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) to generate bromo‐terminated four‐armed PMMA macroinitiators, which further initiate the ATRP of methylacryloyloxyl‐2‐hydroxypropyl perfluorooctanoate (FGOA) to create fluorinated star‐shaped block copolymers PMMA‐b‐poly(FGOA)s with fluorine content ranging from 0 to 31.7 wt %. The polymerizations are well controlled with the polydispersity indices <1.30. The polymers readily dissolve in common organic solvents and show good film‐formation. Compared with the nonfluorinated sample, the fluorinated films exhibit significantly increased water contact angles owing to the enrichment of fluorine on the surface. The enhanced hydrophobicity is advantageous for the optical stability when the devices work under a moist environment. Moreover, the films possess high thermo‐optic coefficients, tunable refractive indices, and extremely low birefringence coefficients because of the presence of bulky and rigid tetraphenylsilane core and star‐shaped topological structure, showing potential application in optical waveguide devices. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 1969–1977 相似文献